Application of Microwave Energy for Production of Iron Nuggets from the Pudo Iron Ore using ‘Pito’ Waste and its Blend with HDPE as Reductant

Authors

  • Mathias Nibebaar Aakyiir University of Mines and Technology
  • James Ransford Dankwah University of Mines and Technology

Keywords:

Reduction, Pudo Iron Ore, Waste Biomass, Pito Waste, Extent of Reduction

Abstract

The local steel industry is currently facing stiff competition from South East Asia and elsewhere for high grade scrap iron, culminating in a ban by central Government on the export of ferrous scrap. In this work we investigate the potential for producing high grade iron nuggets from the Pudo iron ore in the Upper West Region of Ghana, using carbonaceous materials generated from locally available ‘pito’ waste and its blend with high density polyethylene (HDPE) as reductant. Composite pellets of the ore containing various blends of uncharred ‘pito’ and charred ‘pito’ waste with HDPE were irradiated in a domestic microwave oven and the extent of reduction was determined after 40 min of irradiation. It was observed that highly carburised premium grade iron nuggets can be produced from the Pudo iron ore using ‘pito’ waste (both charred and uncharred) and its blends with HDPE as reductant. The measured extent of reduction ranged from about 47 % to about 96 %, suggesting that the Pudo iron ore is a potential source of iron from which premium grade metallic iron can be produced commercially to feed the local steel industry. From the point of view of chemical reactivity, it appears the effect of hydrogen is more pronounced than the amount of fixed carbon in the ‘pito’ waste and this effect was felt in all the HDPE-‘pito’ waste blends utilised for the investigation. Accordingly dry ‘pito’ waste may be used directly with HDPE as reductant without the need to char the biomass.

Author Biographies

Mathias Nibebaar Aakyiir, University of Mines and Technology

Minerals Engineering Department, Teaching Assistant.

James Ransford Dankwah, University of Mines and Technology

Minerals Engineering Department

Senior Lecturer

References

Aakyiir, M.N. and Dankwah, J.R., (2017), Recycling Blends of Waste Groundnut Shells and High Density Polyethylene as Reductants in the Microwave Production of Iron Nuggets from the Pudo Iron Ore. Ghana Journal of Technology, 1(2), pp.45-50.

Abarike, E. D., Attipoe, F. Y. K. and Alhassan, E. H., (2012), “Effects of Feeding Fry of Oreochromis Niloticus on Different Agro-Industrial By-Productsâ€, International Journal of Fisheries and Aquaculture, Vol. 4, No 8, pp. 178-185.

Chen, J.; Liu, L.; Zeng, L.; Zeng, J.Q.; Liu, J.Y. and Ren, R.G. (2003), “Experiment of Microwave Heating on Self-fluxing Pellet Containing Coalâ€, Journal of Iron and Steel Research International, Vol. 10, No. 2, pp. 1-4

Dankwah, J. R., Koshy, P., Saha-Chaudhury, N. M., O'Kane, P., Skidmore, C., Knights, D. and Sahajwalla, V. (2011), “Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and Waste Plasticsâ€, ISIJ International, Vol. 51, No. 3, pp. 498-507.

Dankwah, J. R., Koshy, P., O’Kane, P. and Sahajwalla, V. (2012), “Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and End-of-Life Tyresâ€, Steel Research International, Vol. 83, No.8, pp. 766-774.

Dankwah, J. R., Koshy P. and Sahajwalla, V.H. (2013), “Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and End-of-Life Polyethylene Terephthalateâ€, Ironmaking and Steelmaking, Vol. 41, No. 6, pp. 401-409.

Dankwah, J. R. (2013), “Recycling Blends of Waste Plastics and Biomass as Reducing Agent for the Production of Metallic Iron from Iron Oxideâ€, International Journal of Engineering Science and Technology, Vol. 5, No. 12, pp. 1967-1976.

Dankwah, J. R. (2014), “Recycling Blends of HDPE and Coconut Shells as Reducing Agent for the Production of Metallic Iron from Iron Oxide (Fe2O3)â€, International Journal of Scientific and Technology Research, Vol. 3, Issue 1, pp. 40-46.

Dankwah, J. R. (2014), “Effect of Waste Plastics Addition on the Reduction of Iron Oxide by Sawdust†Proceedings of the Conference of Metallurgists, 28th Sep-1st Oct, 2014, Hyatt Regency Hotel, Vancouver, BC, Canada, pp. 121-130.

Dankwah, J. R., and Koshy, P. (2014), “Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and Waste Polypropyleneâ€. High Temperature Materials and Processes, Vol. 33, No. 2, pp. 107-114.

Dankwah, J. R., Koshy P. and Sahajwalla, V. (2014), “Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and End-of-Life Polyethylene Terephthalateâ€, Ironmaking and Steelmaking, Vol. 41, No. 6, pp. 401-409.

Dankwah, J. R., Baawuah, E., Dankwah, J. and Koshy, P. (2015), “Recycling Mixed Plastic Waste and its Blend with Sawdust as Reductant in Ironmakingâ€. Proceedings of 24th International Mining Congress and Exhibition of Turkey (IMCET 2015), April 14-17, Antalya, Turkey, pp. 1387-1394.

Dankwah, J. R., Fosu, A.Y., Fosu, N. and Koshy, P., (2015), “Carbothermal Upgrading of the Awaso Bauxite Ore using Waste Pure Water Sachets as Reductantâ€, Ghana Mining Journal, Vol. 15, No. 1, pp. 64-72.

Dankwah, J. R., Amoah, T., Dankwah, J. and Fosu, A. Y., (2015), “Recycling Mixed Plastics Waste as Reductant in Ironmakingâ€, Ghana Mining Journal, Vol. 15, No. 2, pp. 73-80.

Ishizaki, K., Nagata, K. and Hayashi, T. (2006), “Production of Pig Iron from Magnetite Ore-Coal Composite Pellets by Microwave Heating, ISIJ International, Vol. 46, No. 10, pp. 1403-1409.

Ishizaki, K. and Nagata, K. (2007), “Selectivity of Microwave Energy Consumption in the Reduction of Fe3O4 with Carbon Black in Mixed Powderâ€, ISIJ International, Vol. 47, No. 6, pp. 811-816.

Kagya-Agyemang, J. K., Nelson, A. and Kagya-Agyemang, C. (2013), “Growth Performance of Weaner Rabbits Fed on Dried Pito Mash as a Replacement for Maizeâ€, ARPN Journal of Agricultural and Biological Science, Vol. 8, No. 4, pp. 267-272.

Kesse, G. O. and Banson, J. K. A. (1975). Iron Ore Deposits of Ghana, A Technical Report by Ghana Geological Survey, No. 7, 54 pp.

Kongkarat, S., Khanna, R., Koshy, P., O’Kane, P., and Sahajwalla, V. (2011), “Use of Waste Bakelite as a Raw Material Resource for Recarburization in Steelmaking Processes†Steel Research International, Vol. 82(10), pp. 1228-1239.

MaÅ¡lejová, A. (2013), “Utilization of Biomass in Ironmakingâ€, Proceedings of 2013 Metal Conference, 15-17. 5. 2013, Brno, Czech Republic, EU, CD-1, pp. 122-127.

Matsuda, T., Takekawa, M., Hasegawa, M., Ikemura, Y., Wakimoto, K., Ariyama, T., and Iwase, M. (2006), “Utilization of Waste Wood for Production of Iron, Carbon Monoxide and Hydrogen without Generating Carbon Dioxideâ€, Steel Res. Int., Vol. 77, pp. 774-784.

Matsuda, T., Hasegawa, M., Ikemura, A., Wakimoto, K., and Iwase, M. (2008), “Utilization of Waste Plastic for Production of Metallic Iron, Hydrogen and Carbon Monoxide without Generating Carbon Dioxideâ€, ISIJ Int., Vol. 48, No. 9, pp. 1186-1196.

Morita, K., Guo, M., Miyazaki, Y. and Sano, N. (2001), “The Heating Characteristics of CaO-SiO2-FeOâ€, ISIJ International, Vol. 41, pp. 716-721.

Mourao, M. B, Parreiras de Carvalho, Jr., I. and Takano, C. (2001), “Carbothermic Reduction by Microwave Heating†ISIJ International., Vol. 41, pp. S27-S30.

Murakami, T., Akiyama, T. and Kasai, E., (2009), “Reduction Behaviour of Hematite Composite containing Polyethylene and Graphite with Different Structures with Increasing Temperatureâ€, ISIJ Int., 49(6), pp. 809-814.

Murakami, T. and Kasai, E., (2011), “Reduction Mechanism of Iron Oxide-carbon Composite with Polyethylene at Lower Temperatureâ€, ISIJ Int., 51(1), pp. 9-13.

Nagata, K., Ishizaki, K. and Hayashi, T. (2004), Proc. of the 5th Japan-Brazil Symp on Dust Processing Energy Environment in Metallurgical Industries, Vol 1, pp. 617.

Nishioka, K., Taniguchi, T., Ueki, Y., Ohno, K., Maeda, T., and Shimizu, M. (2007), “Gasification and Reduction Behaviour of Plastic and Iron Ore Mixtures by Microwave Heatingâ€, ISIJ Int., Vol. 47, No. 4, pp. 602-607.

Standish, N. and Huang, W. (1991), “Microwave Application in Carbothermal Reduction of Iron Oresâ€, ISIJ International, Vol. 31, No. 3, pp. 241-245.

Takayama, S., Link, G., Thumm, M., Matsubara, A., and Sato, M. (2007). “Reduction of Magnetite in Air by use of Microwave Heating. In Vacuum Electronics Conference, 2007. IVEC'07. IEEE International, pp. 1-2.

Ueki, Y., Ohno, K., Maeda, T., Nishioka, K. and Shimizu, M. (2008), “Reaction Behaviour during Heating Waste Plastic Materials and Iron Oxide Compositesâ€, ISIJ Int., Vol. 48, pp. 1670-1675.

Zhong, S., Goetzman, H. E. and Bleifuss, R. L. (1996), “Reduction of Iron Ore with Coal by Microwave Heatingâ€, Minerals and Metallurgical Processing Journal, Vol. 13, No. 4, pp. 174-178.

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Published

2017-06-30

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Section

Minerals Eng. Articles